Well, linear speed of the piston does change. It is slowest when at and near TDC and BDC, fastest halfway between the two.
As to the mirror polishing of the exhaust, I think there may very well be some benefit to it, but I also think it is temporary unless one cleans the carbon from the exhaust tract regularly. Carbon inevitably will start to accumulate no matter how exotic the premix oil one uses or the mix ratio. Some oils are cleaner than others, but in the end carbon deposits will start to form. That is the main reason I have never tried it on my 3 work saws I have ported. Maybe a different story on a race saw that only sees racing action and regular cleaning of carbon is reasonably expected to be done.